The use of heterogeneous and melt miscible nucleating agents for the improvement of the crystallization rate of Poly(hydroxybutyrate-co-hydroxyhexanoate)

Since the 1950s, plastic production has steadily increased with millions of metric tons accumulating in the environment.1 Much of the waste stream is single use plastics, and the need for biodegradable alternatives is pressing. Polyhydroxyalkanoates (PHA), a class of polymers produced by many bacteria as a carbon source, presents a viable biodegradable replacement for many commodity thermoplastics such as polypropylene and polyethylene.

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Rathnaweera Receives Best Poster Award from Materials Research Society

Harshani Rathnaweera, a UGA Chemistry graduate student in the Salguero laboratory, was one of the Materials Research Society’s “Best Poster Winners” at the 2020 Virtual Fall Meeting. Her poster “2D Nanostructured Tetrasilicates with Cr(II) and Cr(II)/Fe(II) in Square-Planar Coordination” described her research on the synthesis, crystal growth, properties, and nanostructuring of metal chromium tetrasilicate materials ACrSi4O10 (A = Ca, Sr, Ba) with interesting magnetic properties.

Photochemical Synthesis and Spectroscopy of Polycyclic Aromatic Hydrocarbon Dimers

Laser desorption time-of-flight mass spectrometry (LD-ToF-MS) experiments on pressed-pellet samples of polycyclic aromatic hydrocarbons (PAHs) produce covalently-bonded dimers at masses (m/z) of 2M-2 and 2M-4 (where M is the parent mass). Through replication of these LD-ToF-MS conditions at higher throughput, PAH dimers have been produced and collected in milligram quantities. For collected samples of pyrene, perylene, and coronene, differential sublimation has isolated the dimer sample from residual monome

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Experimental Catalyst Design Aided by Machine Learning

In the past, catalyst design has been highly characterized by trial and error based on previous experience and knowledge of catalysis.1 Due to the number of variables involved in catalyst performance, it is difficult to manually optimize highly active catalysts. In the past few years, there has been a movement toward the use of machine learning as a tool in experimental catalyst design.

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Insights Into Molecular Structure Via Atomic Force Microscopy

Accurately characterizing the structure of molecules is a fundamental goal for chemists. Many powerful techniques exist to do so (e.g. NMR, IR Spectroscopy, X-ray Crystallography, etc.) and have proven themselves to be extremely effective. However, there are certain cases where these standard ensemble methods struggle to characterize certain systems. In 1986, Binning and coworkers developed Atomic Force Microscopy (AFM) as a complementary method to these traditional techniques.

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