Publications (1956-1969)
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1. The Dehydration of exo-Trimethylene-2-exo-Norbornanol. Paul von Ragué Schleyer and Malcolm M. Donaldson. J. Am. Chem. Soc. 1956, 78, 5702.
2. A Simple Preparation of Adamantane. Paul von Ragué Schleyer. J. Am. Chem. Soc. 1957, 79, 3292.
3 . The Relative Stability of Bridged Hydrocarbons. Nor- bornene and Nortricyclene. Paul von Ragué Schleyer. J.Am.Chem.Soc. 1958, 80, 1700-1704. 4. Intramolecular Hydrogen Bonding Involving Double Bonds, Triple Bonds, and Cyclopropane Rings as Proton Acceptors. Paul von Ragué Schleyer, Daniel S. Trifan, and Robert Bacskai. J. Am. Chem. Soc. 1958, 80, 6691- 6692.
5. Comparison of Covalently Bonded Electronegative Atoms as Proton Acceptor Groups in Hydrogen Bonding. Paul von Ragué Schleyer and Robert West. J. Am. Chem. Soc. 1959, 81, 3164-3165. 6. Hydrogen Bonding in ß-Aryl Ethanols. Paul von Ragué Schleyer, C. Winter, D.S. Trifan, and R. Bacskai. Tetrahedron Lett. 1959, 1-7.
7. Addition Reactions of exo-Trimethylene-2-norbornene. L. Kaplan, H. Kwart, and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1960, 82, 2341-2347.
9. The Preparation and Reactivity of 2-Substituted Der- ivatives of Adamantane. Paul von Ragué Schleyer and Robert D. Nicholas. J. Am. Chem. Soc. 1961, 83, 182- 187. 10. The Thorpe-Ingold Hypothesis of Valency Deviation. Intramolecular Hydrogen Bonding in 2-Substituted Propane-1,3-diols. Paul von Ragué Schleyer. J. Am. Chem. Soc. 1961, 83, 1368-1373. 11. The Reactivity of Bridgehead Compounds of Adamantane. Paul von Ragué Schleyer and Robert D. Nicholas. J. Am. Chem. Soc. 1961, 83, 2700-2707. 12. Aryl Norbornane Derivatives. I. Preparation of Compounds. Donald C. Kleinfelter and Paul von Ragué Schleyer. J. Org. Chem. 1961, 26, 3740-3751. 13. Aryl Norbornane Derivatives. II. The Unusual Prep- aration of a Carbonate during Performic Acid Oxid- ation. Donald C. Kleinfelter and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1961, 83, 2329-2335. 14. Further Examples of the Adamantane Rearrangement. Paul von Ragué Schleyer and Robert D. Nicholas. Tetrahedron Lett. 1961, 9, 305-309. 15. Long-Range N14-H1 Nuclear-Resonance Coupling in Iso- nitriles. I. D. Kuntz, Jr., Paul von Ragué Schleyer, and A. Allerhand. J. Chem. Phys. 1961, 35, 1533-1534. 16. A Novel Convenient Synthesis of Arylnorbornyl Cations. Norman C. Deno, Paul von Ragué Schleyer, and Donald C. Kleinfelter. Tetrahedron Lett. 1961, 12, 414-416.
17. Adamantane (Tricyclo[3.3.1.13,7]decane). Paul von Ragué Schleyer, M.M. Donaldson, R.D. Nicholas, and C. A. Cupas. Org. Syn. 1962, 42, 8-11. 18. 2-Norbornanone (Norcamphor). Donald C. Kleinfelter and Paul von Ragué Schleyer. Org. Syn. 1962, 42, 79-82. 19. Strong Hydrogen Bonds to Carbon in Isocyanides. Paul von Ragué Schleyer and Adam Allerhand. J. Am. Chem. Soc. 1962, 84, 1322-1323. 20. The Relative Strengths of Alkyl Halides as Proton Acceptor Groups in Hydrogen Bonding. Robert West, David L. Powell, Linda S. Whatley, Margaret K.T. Lee, and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1962, 84, 3221-3222.
21. Quantitative Study of the Interconversion of Hydrindane Isomers by Aluminum Bromide. Kenneth B. Blanchard and Paul von Ragué Schleyer. J. Org. Chem. 1963, 28, 247-248. 22. Solvent Effects in Infrared Spectroscopic Studies of Hydrogen Bonding. Adam Allerhand and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1963, 85, 371-380. 23. Non-Classical Carbonium Ions: The Structure of Stable Aryl Substituted Norbornyl Cations. Paul von Ragué Schleyer, Donald C. Kleinfelter, and Herman G. Richey, Jr. J. Am. Chem. Soc. 1963, 85, 479-481. 24. Nitriles and Isonitriles as Proton Acceptors in Hydrogen Bonding: Correlation of AtOH with Acceptor Structure. Adam Allerhand and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1963, 85, 866-870. 25. Halide Anions as Proton Acceptors in Hydrogen Bonding. Adam Allerhand and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1963, 85, 1233-1237. 26. Predominant Importance of Entropy on Relative Stabilities of Bicyclooctane Isomers. Paul von Ragué Schleyer, Kenneth R. Blanchard, and Charles D. Woody. J. Am. Chem. Soc. 1963, 85, 1358-1359. 27. A Survey of C-H Groups as Proton Donors in Hydrogen Bonding. Adam Allerhand and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1963, 85, 1715-1725. 28. Ring Size Effect on cis-Olefinic Coupling Constants of Cycloalkanes. Use of 13C Patterns. Pierre Laszlo and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1963, 85, 2017-2018. 29. Electronegativity of Substituents and Nuclear Magnetic Resonance Spectra of Norbornene Derivatives. Pierre Laszlo and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1963, 85, 2709-2712.
30. Constantes de Couplage et Structure en Résonance magnétique nucléaire. Les Couplages Vicinaux des Ethylenes-1,2 Disubstitués. Pierre Laszlo et Paul von Ragué Schleyer. Bull. Soc. Chim. France 1964, 87-89. 31. Conformational Effects and Hydrogen Bonding in 1,4- Diols. Lester P. Kuhn, Paul von Ragué Schleyer, William F. Baitinger, Jr., and Lennart Eberson. J. Am. Chem. Soc. 1964, 86, 650-658. 32. Hydrogen Bonding in 1,4-Substituted Butane-1,4-diols. William F. Baitinger and Paul von Ragué Schleyer. J. Org. Chem. 1964, 29, 989-990. 33. Analysis of the Nuclear Magnetic Resonance Spectra of Norbornene Derivatives. Pierre Laszlo and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1964, 86, 1171-1179. 34. Estimation of Nonassisted Solvolysis Rates. Paul von Ragué Schleyer. J. Am. Chem. Soc. 1964, 86, 1854-1856. \35. The Nonclassical Carbonium Ion Problem: Reaction Rates. Paul von Ragué Schleyer. J. Am. Chem. Soc. 1964, 86, 1856-1857. 36. Adamantane: Consequences of the Diamondoid Structure. Raymond C. Fort, Jr. and Paul von Ragué Schleyer. Chemical Reviews 1964, 64, 277-300. 37. Nitro Groups as Proton Acceptors in Hydrogen Bonding. W.F. Baitinger, Paul von Ragué Schleyer, T.S.S.R. Murty, and L. Robinson. Tetrahedron 1964, 20, 1635- 1647. 38. Estimation of Nonassisted Solvolysis Rates. The Structures of the "Nopinyl p-Bromobenzenesulfonates". Paul von Ragué Schleyer, William E. Watts, and Chris Cupas. J.Am. Chem. Soc. 1964, 86, 2722-2723. 39. Valence Isomerization of Cis-1,2-Divinylcyclopropanes: A Simple Synthesis of Bicyclo[3.2.1]Octadiene. Chris Cupas, W.E. Watts, and Paul von Ragué Schleyer. Tetrahedron Lett. 1964, 2503-2507. 40. Bridgehead Adamantane Carbonium Ion Reactivities. Raymond C. Fort, Jr. and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1964, 86, 4194-4195. 41. Stable Carbonium Ions. VIII. The 1-Adamantyl Cation. Paul von Ragué Schleyer, Raymond C. Fort, Jr., William E. Watts, Melvin B. Comisarow, and George A. Olah. J. Am. Chem. Soc. 1964, 86, 4195-4197. 42. Stable Carbonium Ions. X. Direct Nuclear Magnetic Resonance Observation of the 2-Norbornyl Cation. Paul von Ragué Schleyer, William E. Watts, Raymond C. Fort, Jr., Melvin, B. Comisarow, and George A. Olah. J. Am. Chem. Soc. 1964, 86, 5679- 5680. 43. Stable Carbonium Ions. XI. The Rate of Hydride Shifts in the 2-Norbornyl Cation. Martin, Saunders, Paul von Ragué Schleyer, and George A. Olah. J. Am. Chem. Soc. 1964, 86, 5680-5681.
44. Substituted Effects on 2-Norbornyl Solvolysis Rates. The 6,6-Dimethyl Group. Paul von Ragué Schleyer, Malcolm M. Donaldson, and William E. Watts. J. Am. Chem. Soc. 1965, 87, 375-376. 45. Congressane. Chris Cupas, Paul von Ragué Schleyer, and David J. Trecker. J. Am. Chem. Soc. 1965, 87, 917-918. 46. The Proton Magnetic Resonance Spectra of Adamantane and its Derivatives. Raymond C. Fort, Jr. and Paul von Ragué Schleyer. J. Org. Chem. 1965, 30, 789-796. 47. Hydrogen Bonding in ortho-Substituted Biphenyls. William F. Baitinger, Jr., Paul von Ragué Schleyer, and Kurt Mislow. J. Am. Chem. Soc. 1965, 87, 3168- 3173.
48. Substituent Effects on Cyclopropylcarbinyl Solvolysis Rates. Evidence for Symmetrical Transition States. Paul von Ragué Schleyer and George W. van Dine. J. Am. Chem.Soc. 1966, 88, 2321-2322. 49. Adamantane Rearrangements. The Isomerization of Dihydrocedrene to 1-Ethyl-,5,7-trimethyladamantane. Paul von Ragué Schleyer, Gerald Jay Gleicher, and Chris A. Cupas. J. Org. Chem. 1966, 31, 2014-2015. 50. Bridgehead Reactivity. Paul von Ragué Schleyer and Raymond C. Fort, Jr."Advances in Alicyclic Chemistry". (Ed. H. Hart and G.J. Karabatsos) Vol. I.; Academic Press Inc. 1966, p.283-370. 51. Steric and Electrocyclic Control of Cyclopropyl Tosylate Solvolysis Rates. Paul von Ragué Schleyer, George W. van Diene, Ulrich Schllkopf, and Joachim Paust. J. Am. Chem. Soc. 1966, 88, 2868-2869. 52. Triamantane. Van Zandt Willians, Jr., Paul von Ragué Schleyer, Gerald Jay Gleicher, and Lynn B. Rodewald. J. Am. Chem. Soc. 1966, 88, 3862-3863. 53. Solvolysis of 1-Adamantylcarbinyl and 3-Homoadamantyl Derivatives. Mechanism of the Neopentyl Cation Rearrangement. J. Eric Nordlander, Satya P. Jindal, Paul von Ragué Schleyer, Raymond C. Fort, Jr., Jon J. Harper, and Robert d. Nicholas. J. Am. Chem. Soc. 1966, 88, 4475-4484. 54. The Slow Rates of Solvolysis of endo-5,6- Trimethylene-endo-(2 and 8)-norbornyl Tosylates - Steric Hindrance to Ionization and the Foote- Schleyer Correlation. Paul von Ragué Schleyer, Herbert C. Brown, Irvin Rothberg, Malcolm M. Donaldson, and Jon J. Harper. Proc. Nat. Acad. Sci. 1966, 56, 1653-166.
55. Conformational Analysis of Bridgehead Carbonium Ions. Gerald Jay Gleicher and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1967, 89,582593. 56. The Degenerate Paul von Ragué Schleyer, Jon J. Harper, George L. Dunn, Vincent J. DiPasquo, and J.R.E. Hoover. J. Am. Chem. Soc. 1967, 89, 698- 699. 57. Torsional Effects in Polycyclic Systems. I. The Stereochemistry of 3,2 Shifts in Norbornyl Cations. Paul von Ragué Schleyer. J. Am. Chem. Soc. 1967, 89, 699-701. 58. Torsional Effects in Polycyclic Systems. II. The Stereochemistry of Attack and Departure in Norbornane Derivatives. Paul von Ragué Schleyer. J. Am. Chem. Soc. 1967, 89, 701-703. 59. Noradamantane by Aluminum Halide Catalyzed Rearrangement. Paul von Ragué Schleyer and Erik Wiskott. Tetrahedron Letters 1967, 2845-2850. 60. Alkyladamantanes by Rearrangement from Diverse Starting Materials. M. Nomura, Paul von Ragué Schleyer, and A.A. Arz. J. Chem. Soc. 1967, 89, 3657- 3659. 61. Protonic Acid Additions to 1-Methylnorbornene. The Absence of Orientational Control Attributable to Participation. Paul von Ragué Schleyer. J. Am. Chm. Soc. 1967, 89, 3901-3903. 62. Valenzisomerisierung von Kohlenwasserstoffen, die dreigliedrige Ringe enthalten. E. Wiskott und P.v.R. Schleyer. Angew. Chem. 1967, 79, 680-681. Valence Isomerization Involving Cyclopropane- Containing Hydrocarbons. Angew. Chem. Int. Ed. Engl. 1967, 6, 694-695. 63. Acetolyse von Endo- und Exo-Bicyclo-(n,1,0)-Alkyl- Tosylaten. U. Schllkopf, K. Fellenberger, M. Patsch, P.v.R. Schleyer, T. Su und G.W. van Dine. Tetrahedron Letters 1967, 3639-3644. 64. Hydrogen Bonding. I. Two Approaches to Accurate Heats of Formation. Edward M. Arnett, T.S.S.R. Murty, Paul von Ragué Schleyer, and L. Joris. J. Am. Chem. Soc. 1967, 89, 5955-5957. 65. Regarding Proton Transfer in Hydrogen-Bonded Complexes as Measured by Fluorine Nuclear Magnetic Resonance. D. Gurka, R.W. Taft, L. Joris, and P.v.R. Schleyer. J. Am. Chem. Soc. 1967, 89, 5957-5958. 66. Thermal Instability of 1- and 2-Norbornyl and of 1- Bicyclo[2.2.2]octyl Radicals in a Mass Spectrometer. T. McAllister, Z. Dolesek, F.P. Lossing, R. Gleiter, and P.v.R. Schleyer. J. Am. Chem. Soc. 1967, 89, 5982- 5983.
67. Cyclopropane Rings as Proton-Acceptor Groups in Hydrogen Bonding. Louis Joris, Paul von Ragué Schleyer, and Rolf Gleiter. J. Am. Chem. Soc. 1968, 90, 327-336. 68. Bridgehead Reactivity in Bicyclo[3.3.1]nonane Systems. Paul von Ragué Schleyer, Peter R. Isele, and Richard C. Bingham. J. Org. Chem. 1968, 33, 1239-1240. 69. Infrared Spectral Consequences of Conformational Heterogeneity in Saturated Alcohols. L. Joris, P.v.R. Schleyer, and E. Osawa. Tetrahedron 1968, 24, 4759- 4777. 70. Intramolecular Hydrogen Bonding in Aliphatic Hydroxy Ketones. Louis Joris and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1968, 90, 4599-4611. 71. -Deficient N-Heteroaromatics as Proton Acceptors in Hydrogen-Bonding. Infrared Spectral Shifts vs. pKa's as Measures of "Basicity". Louis Joris and Paul von Ragué Schleyer. Tetrahedron 1968, 24, 5991-6005. 72. Hydrogenolysis of Cyclopropane Derivatives. Application to the Synthesis of an Axial t- Butylcyclohexane, 2-t-Butyladamantane. Curtis W. Woodworth, Volker Buss, and Paul von Ragué Schleyer. Chem. Comm. 1968, 569-570. 73. Valenzisomerisierungen von C9H10-Kohlenwasserstoffen. J. Daub und P.v.R. Schleyer. Angew. Chem. 1968, 80, 446-447. Valence Isomerization of C9H10 Hydrocarbons. Angew. Chem. Int. Ed. Engl. 1968, 7, 468-469. 74. Physical Organic Chemistry: Quantitative Conformational Analysis; Calculation Methods. James E. Williams, Peter J. Stang, and Paul von Ragué Schleyer.Ann. Rev. Phys. Chem. 1968, 19, 531-558. 75. The 5-Tetracyclo[4.3.0.02,4.03,7]non-8-enyl Cation. A Curious Case of Nonrearrangement in a C9H9+ System. Paul von Ragué Schleyer and Ronald E. Leone. J. Am. Chem. Soc. 1968, 90, 4164-4165. 76. Nonacyclo[11.71.12,18.03,16.04,13.06,14.07,11.015,20]- docosane, a Bastard Tetramantane. Paul von Ragué Schleyer, Eiji Osawa, and Michael G.B. Drew. J. Am. Chem. Soc. 1968, 90, 5034-5036. 77. Substituents and Bridgehead Carbonium Ion Reactivities. Inductive and Steric Effects of Alkyl Groups in Saturated Systems. Paul von Ragué Schleyer and Curtis W. Woodworth. J. Am. Chem. Soc. 1968, 90, 6528-6530. 78. Nitrene Insertion Selectivities. The Reaction of Ethyl Azidoformate with Saturated Cyclic Hydrocarbons. David S. Breslow, Eleanor I. Edwards, Ronald Leone, and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1968, 90, 7097- 7102. 79. The Stereochemical Course of the Hydrogenolysis of Cyclopropane Rings. Zdenko Majerski and Paul von Ragué Schleyer. Tetrahedron Letters 1968, 6195-6196.
80. Can Deformed Classical Carbonium Ions be Nonplanar? James E. Williams, Jr., Reiner Sustmann, Leland C. Allen, and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1969, 91, 1037-1038. 81. The Absolute Configuration of Pinacolyl Alcohol. John Jacobus, Zdenko Majerski, Kurt Mislow, and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1969, 91, 1998-2000. 82. Homoadamantane. I. A New Synthesis. Conformational Evidence. The Degenerate 4-Homoadamantyl Cation. Paul von Ragué Schleyer, Eberhard Funke, and Samuel H. Liggero. J. Am. Chem. Soc. 1969, 91, 3965-3967. 83. Participation by Neighboring Aryl Groups. I. Determination of Assisted and Nonassisted Solvolysis Rates by Hammett Correlation. Charles J. Lancelot and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1969, 91, 4291-4294. 84. Participation by Neighboring Aryl Groups. II. Accurate Determinations of Inductive and Anchimeric Assistance Effects by a Hammett-Taft Correlation. Charles J. Lancelot, Jon J. Harper, and Paul von Ragué Schleyer.J. Am. Chem. Soc. 1969, 91, 4294-4296. 85. Participation by Neighboring Aryl Groups. III. Accurate Determination of Inductive and Anchimeric Assistance Effects by a Novel Multiple Substitution Technique. Charles J. Lancelot and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1969, 91, 4296-4297. 86. Participation by Neighboring Aryl Groups. IV. Correspondence of Rate and Product Data. Mechanistic Significance. Paul von Ragué Schleyer and J. Lancelot. J. Am. Chem. Soc. 1969, 91, 4297-4300. 87. The Acetolysis of Chiral 1-Adamantylcarbinyl-1'-d Tosylate. Evidence for a Bridged Intermediate in a Neopentyl Solvolysis. Samuel H. Liggero, Reiner Sustmann, and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1969, 91, 4571-4573. 88. Studies of Hydrogen-Bonded Complex Formation with p- Fluorophenol. V. Linear Free Energy Relationships with OH Reference Acids. R.W. Taft, D. Gurka, L. Joris, P.v.R. Schleyer, and J.W. Rakshys. J. Am. Chem. Soc. 1969, 91, 4801-4808. 89. The Stereochemistry of Allyl Cations for the Isomeric 2,3-Dimethylcyclopropyl Chlorides. The Stereomutation of Allyl Cations. Paul von Ragué Schleyer, Tah Mun Su, Martin Saunders, and Jerold C. Rosenfeld. J. Am. Chem. Soc. 1969, 91, 5174-5176. 90. A New Synthesis of Dicyclopropylcarbinoxymethanes - By-Products in the Simmons-Smith Reaction with Allyl Alcohols. Zdenko Majerski and Paul von Ragué Schleyer. J. Org. Chem. 1969, 34, 3215-3216. 91. Molecular Orbital Calculations on Carbonium Ions. II. The Methyl, Ethyl, and Vinyl Cations. The Series C3H7+. R. Sustmann, J.E. Williams, M.J.S. Dewar, L.C. Allen, and P.v.R. Schleyer. J. Am. Chem. Soc. 1969, 91, 5350-5357. 92. The Solvolysis of Highly Unreactive Substrates Using the Trifluoromethanesulfonate (Triflate) Leaving Group. Tah Mun Su, Wallace F. Sliwinski, and Paul von Ragué Schleyer. J. Am. Chem. Soc. 1969, 91, 5386-5388. 93. Cationic Destabilization in a Geometrically Restricted Cyclopropylcarbinyl System. Paul von Ragué Schleyer and Volker Buss. J. Am. Chem. Soc. 1969, 91, 5880- 5882. 94. Homoadamantane. II. Analysis of the NMR Spectrum of Homoadamantane. Samuel H. Liggero, Paul von Ragué Schleyer, and Kermit C. Ramey. Spectroscopy Letters 1969, 2, 197-201. 95. Solvolysis of t-Butyl Substituted Cyclobutyl Tosylates. Paul von Ragué Schleyer, P. LePerchec, and Douglas J. Raber. Tetrahedron Letters 1969, 50, 4389- 4392. 96. High exo:endo Rate Ratios in the Solvolysis of the 2- Methyl- and 2-Phenyl-exo-5,6-trimethylene-2-norbornyl p-Nitrobenzoates. Evidence for the Unimportance of r Participation in the High exo:endo Rate Ratios in Tertiary Norbornyl Derivatives. Herbert C. Brown, David L. Vander Jagt, Paul von Ragué Schleyer, Raymond C. Fort, Jr., and William E. Watts. J. Am. Chem. Soc. 1969, 91, 6848-6850. 97. Participation by Neighboring Aryl Groups. V. Determinations of Assisted and Nonassisted Rates in Primary Systems. Rate-Product Correlations. J. Milton Harris, Frank L. Schadt, Paul von Ragué Schleyer, and Charles L. Lancelot. J. Am. Chem. Soc. 1969, 91, 7508- 7510. 98. Degenerate Rearrangements of the 9-Barbaralyl Cation. J.C. Barborak, J. Daub, D.M. Follweiler, and P.v.R. Schleyer. J. Am. Chem. Soc. 1969, 91, 7760-7761.
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